The Dark Knight - Gotham City Bank
404 W Harrison St, Old Chicago Post Office
The Dark Knight (2008), second in Christopher Nolan's Batman trilogy, had many filming locations around Chicago. This location, the Old Chicago Post Office, served as the Gotham City Bank in the opening heist sequence of the film, in which the Joker successfully robs the bank and then escapes in a school bus.
(Fun Fact: In the above photo Joker is standing at the southwest corner of Franklin/Van Buren, facing away from the bank building)